Unlock: Available from start

Technique*********************************** : Button
‰e•ªg‚Ìp (Kage Bunshin no Jutsu)********** : R1
—†ùŠÛ (Rasengan)*************************** : R2
* ‚¨‚¢‚낯‚Ìp (Oiroke no Jutsu)************ : R1+R2
ƒn[ƒŒƒ€‚Ìp (Harem no Jutsu)*************** : When using Kage Bunshin, R1+R2
* ‚¤‚¸‚Ü‚«ƒiƒ‹ƒg˜A’e (Uzumaki Naruto Rendan) : Lock on, in midair, R1+R2
* ^‚Ì—†ùŠÛ (Shin no Rasengan)************* : Hold R2

Awakening:
܋Ӛ (Kyuubi) : When spirit gauuge is max (top left), Triangle + Circle

Udedamashi Item:
ƒiƒ‹ƒg‚Ì—E‹C (Naruto's Courage) : HP/chakra up 100, chakra recovers slowly


03b) t–ìƒTƒNƒ‰
**** Haruno Sakura

Unlock: Finish 1st episode of story

Technique******************************** : Button
Õ”g—‚êç‚«***************************** : R1
Õ”gˆê—ÖŽh‚µ***************************** : R2
* ƒTƒNƒ‰á‚Ìp (Sakura Fubuki no Jutsu) : R1+R2

Udedamashi Item:
ƒTƒNƒ‰‚ÌŠó–] (Sakura's Hope) : Taijutsu Atk/Def up 50


03c) ‚Í‚½‚¯ƒJƒJƒV
**** Hatake Kakashi

Unlock: Finish 1st episode of story

Technique************************* : Button
‰e•ªg‚Ìp (Kage Bunshin no Jutsu) : R1
—‹Ø (Raiki)********************** : R2
* ŽÔ—ÖŠá (Sharingan)************** : R1+R2

Udedamashi Item:
ƒJƒJƒV‚ÌŽÀ—Í (Kakashi's Real Power) : Ninjutsu Atk/Def up 50


03d) “ޗǃVƒJƒ}ƒ‹
**** Nara Shikamaru

Unlock: Finish 3rd episode of story

Technique********************** : Button
ƒgƒ‰ƒbƒvƒNƒiƒC (Trap Kunai)**** : R1
‰e^Ž—‚Ìp (Kage Mane no Jutsu) : R2
* ‰e–Ô‚Ìp (Kage Ami no Jutsu)* : R1+R2

Udedamashi Item:
ƒVƒJƒ}ƒ‹‚Ì“ª”] (Shikamaru's Brains) : Ninjutsu Def up 50,
************************************* Ninjutsu damage down 20%


03e) H“¹ƒ`ƒ‡ƒEƒW
**** Akimichi Chouji

Unlock: Finish 6th episode of story

Technique************************** : Button
“÷’eíŽÔ (Nikudan Sensha)********** : R1
•”•ª”{‰Á‚Ìp (Bubun Baika no Jutsu) : R2
* ”{‰Á‚Ìp (Baika no Jutsu)******** : R1+R2

Udedamashi Item:
ƒ`ƒ‡ƒEƒW‚Ì—Fî (Chouji's Friendship) : Taijutsu Def up 50,
************************************** Taijutsu damage down 20%


03f) “úŒüƒlƒW
**** Hyuuga Neji

Unlock: Finish 2nd episode of story

Technique****************************** : Button
”ªŒT¶E‰ñ“] (Hakkeshou Kaiten)******** : R1
_Π(Jyuken)************************** : R2
* ”ªŒT˜Z\Žl¶ (Hakke Rokujyuuyon Shou) : R1+R2

Udedamashi Item:
ƒlƒW‚ÌË”\ (Neji's Talent) : Chakra up 100, Ninjutsu Atk up 30


03g) ƒƒbƒNEƒŠ[
**** Rock Lee

Unlock: Finish 5th episode of story

Technique***************************** : Button
ƒ_ƒCƒiƒ~ƒbƒNƒGƒ“ƒgƒŠ[ (Dynamic Entry) : R1
–؃m—t‘åù•— (Konoha Daisenpuu)******* : R2
* •\˜@‰Ø (Omote Renge)**************** : R1+R2
—*˜@‰Ø (Ura Renge)******************** : R1+R2

Awakening:
”ª–å“Ùb: When spirit gauuge is max (top left), Triangle + Circle

Udedamashi Item:
ƒŠ[‚Ì“w—Í (Lee's Effort) : Health up 100, Taijutsu Atk up 30


03h) ƒ}ƒCƒgEƒKƒC
**** Maito Gai

Unlock: Finish 8th episode of story

Technique***************************** : Button
ƒ_ƒCƒiƒ~ƒbƒNƒGƒ“ƒgƒŠ[ (Dynamic Entry) : R1
–؃m—t‘åù•— (Konoha Daisenpuu)******* : R2
* •\˜@‰Ø (Omote Renge)**************** : R1+R2
—*˜@‰Ø (Ura Renge)******************** : R1+R2

Awakening:
”ª–å“Ùb: When spirit gauuge is max (top left), Triangle + Circle

Udedamashi Item:
ƒKƒC‚Ì”MŒŒ (Gai's Hot Blood) : Health up 100, Taijutsu Atk up 30


03i) ‰äˆ¤—…
**** Gaara

Unlock: Finish 9th episode of story

Technique***************** : Button
»Žž‰J (Suna Shigure)***** : R1
»w•Ç (Suna Jinheki)***** : R2
* »”™‘—‘’ (Sabaku Sousou) : R1+R2

Udedamashi Item:
‰äˆ¤—…‚ÌãJ (Gaara's Bonds) : Ninjutsu Atk up 50, Taijutsu Def up 50


03j) ƒJƒ“ƒNƒƒE
**** Kankurou

Unlock: Available from start

Technique************ : Button
—ŽË”²*************** : R1
‹óP’e (Kuushuu Tama) : R2
* —•‘ (Ranbu)******* : R1+R2

Udedamashi Item:
ƒJƒ“ƒNƒƒE‚ÌŽ©M (Kankurou's Self Confidence) : Taijutsu Atk up 50,
*********************************************** Ninjutsu Def up 50


03k) ‚¤‚¿‚̓TƒXƒP
**** Uchiha Sasuke

Unlock: Clear story mode twice

Technique********************************** : Button
‰Î“ÙE–På‰Î‚Ìp (Katon: Housenka no Jutsu) : R1
ç’¹ (Chidori)***************************** : R2
* Ž‚Žq˜A’e (Shishi Rendan)***************** : R1+R2

Udedamashi Item:
ƒTƒXƒP‚Ì“¬Žu (Sasuke's Fighting Spirit) : Taijutsu Atk up 50,
***************************************** Ninjutsu Atk up 50


03l) ‚¤‚¿‚̓Cƒ^ƒ`
**** Uchiha Itachi

Unlock: Clear Kakashi Gaiden

Technique*********************************** : Button
‰e•ªgR‚è (Kage Bunshin Keri)************** : R1
‰Î“ÙE‹‰Î‹…‚Ìp (Katon: Goukakyuu no Jutsu) : R2
ŒŽ“Ç (Tsukiyomi)**************************** : R1+R2


03m) Š±Š`‹SŽL
**** Hoshikagi Kisame

Unlock: Clear Kakashi Gaiden

Technique************************************ : Button
…•ªg‚Ìp (Sui Bunshin no Jutsu)************ : R1
…“ÙE…˜S‚Ìp (Suiton: Mizurou no Jutsu)**** : R2
…“ÙE‘åàe•z‚Ìp (Suiton: Daibakufu no Jutsu) : R1+R2

(from gamefaqs.com)